Well, figured out the source of the leak, and silicone sealer wasn't going to help. My replacement windshield was still under warranty 13 years later, so I gave them a call and they came out and removed the windshield, found lots of surface rust (but nothing deep or perforating) all across the top beneath the windshield seal. They brushed down to white metal, primed, and installed a new windshield, all for zero dollars. It'll sit in the garage for at least two days, and then through the car wash to check. Don't know how long it'll hold, but I'm sure pleased with the service received--had to be $300 worth of glass & labor. For info to others with a similar problem, I'd been chasing minor leaks for a couple of years at least (center windshield into the overhead console, minor trickle directly in front of the driver, and then this leak down the A pillar) with no external indication of rust along the roof line.